Online ISSN: 1521-3773 Print ISSN: 1433-7851
Angewandte Chemie International Edition
Volume
39, Issue
12,
2000.
© 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
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Online ISSN: 1521-3773 Print ISSN: 1433-7851 © 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany |
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Cover Picture Thomas M. Klapötke, Heinrich Nöth, Thomas Schütt, Marcus Warchhold Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2023::AID-ANIE2023>3.0.CO;2-A |
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The Tetracycline Repressor - A Paradigm for a Biological Switch Wolfram Saenger, Peter Orth, Caroline Kisker, Wolfgang Hillen, Winfried Hinrichs Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2042::AID-ANIE2042>3.0.CO;2-C |
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Conformation Design of Open-Chain Compounds Reinhard W. Hoffmann Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2054::AID-ANIE2054>3.0.CO;2-Z |
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A Diborane Story Pierre Laszlo Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2071::AID-ANIE2071>3.0.CO;2-C |
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Synthesis of Medium-Sized Rings by the Ring-Closing Metathesis Reaction Martin E. Maier Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2073::AID-ANIE2073>3.0.CO;2-0 |
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New Sulfur- and Selenium-Based Traceless Linkers - More than just Linkers? Florencio Zaragoza Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2077::AID-ANIE2077>3.0.CO;2-D |
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A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4-bipyridine)2}n] Shin-ichiro Noro, Susumu Kitagawa, Mitsuru Kondo, Kenji Seki Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2081::AID-ANIE2081>3.0.CO;2-A |
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Structure and Mechanism in Cinchona Alkaloid Chemistry: Aqueous Hydrolysis Proceeds with Complete Inversion or Complete Retention of Configuration Wilfried. M. Braje, Jens Holzgrefe, Rudolf Wartchow, H. Martin R. Hoffmann Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2085::AID-ANIE2085>3.0.CO;2-N |
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P6 Manganocene and P3 Cymantrene: Consequences of the Inclusion of Phosphorus Atoms in Mn-Coordinated Cyclopentadienyl Ligands Timothy Clark, Achim Elvers, Frank W. Heinemann, Matthias Hennemann, Matthias Zeller, Ulrich Zenneck Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2087::AID-ANIE2087>3.0.CO;2-B |
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Triple-Decker Type Coordination of a Fullerene Trianion in [K([18]crown-6)]3[6,6-C60](3-C6H5CH3)2 - Single Crystal Structure and Magnetic Properties
Thomas F. Fässler, Rudolf Hoffmann, Stefan Hoffmann, Michael Wörle Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2091::AID-ANIE2091>3.0.CO;2-8 |
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The Valence Isomerization of Cyclooctatetraene to Semibullvalene
Obis Castańo, Luis-Manuel Frutos, Raúl Palmeiro, Rafael Notario, Jos?Luis Andrés, Roberto Gomperts, Luis Blancafort, Michael A. Robb Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2095::AID-ANIE2095>3.0.CO;2-L |
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Application of 3D-TOCSY-trNOESY for the Assignment of Bioactive Ligands from Mixtures Lars Herfurth, Thomas Weimar, Thomas Peters Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2097::AID-ANIE2097>3.0.CO;2-9 |
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Natural-Product Hybrids: Design, Synthesis, and Biological Evaluation of Quinone-Annonaceous Acetogenins Sabine Hoppen, Ulrich Emde, Thorsten Friedrich, Lutz Grubert, Ulrich Koert Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2099::AID-ANIE2099>3.0.CO;2-Y |
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Synthesis of Trioxane Using Heteropolyacids as Catalyst Junzo Masamoto, Katsuhiko Hamanaka, Kohichi Yoshida, Hajime Nagahara, Kenji Kagawa, Toshiyuki Iwaisako, Hajime Komaki Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2102::AID-ANIE2102>3.0.CO;2-E |
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Enantioselective Synthesis of Functionalized 1,5-Cyclononadienes by Intramolecular Cycloalkylation under ,-Diallyl Coupling
Alexander Deiters, Roland Fröhlich, Dieter Hoppe Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2105::AID-ANIE2105>3.0.CO;2-X |
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Tetraphenylphosphonium Hexaazidoarsenate(V): The First Structurally Characterized Binary AsV-Azide Species
Thomas M. Klapötke, Heinrich Nöth, Thomas Schütt, Marcus Warchhold Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2108::AID-ANIE2108>3.0.CO;2-F |
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Preparation of Bioconjugates through an Ugi Reaction Thomas Ziegler, Sonja Gerling, Martin Lang Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2109::AID-ANIE2109>3.0.CO;2-9 |
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4-Peroxo versus Bis(2-Hydroxo) Cores in Structurally Analogous Tetracopper(II) Complexes Franc Meyer, Hans Pritzkow Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2112::AID-ANIE2112>3.0.CO;2-C |
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The Use of Immobilized Templates - A New Approach in Molecular Imprinting Ecevit Yilmaz, Karsten Haupt, Klaus Mosbach Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2115::AID-ANIE2115>3.0.CO;2-V |
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Synthesis and Reactivity of [{(CO)5Cr}3Pb]2-, an Unsaturated Compound with Trigonal-Planar Coordinated Lead Peter Rutsch, Gottfried Huttner Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2118::AID-ANIE2118>3.0.CO;2-D |
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Metal-Based NO Sensing by Selective Ligand Dissociation Katherine J. Franz, Nisha Singh, Stephen J. Lippard Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2120::AID-ANIE2120>3.0.CO;2-M |
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Guest Penetration Deep within the Cavity of Calix[4]arene Hosts: The Tight Binding of Nitric Oxide to Distal (Cofacial) Aromatic Groups Rajendra Rathore, Sergey V. Lindeman, Kolluri S. S. P. Rao, Duoli Sun, Jay K. Kochi Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2123::AID-ANIE2123>3.0.CO;2-4 |
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A Transition State for the Enantioselective Deprotonation of N-Boc-Pyrrolidine with Isopropyllithium/(-)-Sparteine Kenneth B. Wiberg, William F. Bailey Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2127::AID-ANIE2127>3.0.CO;2-H |
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Chiral Guests and Their Ghosts in Reversibly Assembled Hosts
Jos?M. Rivera, Stephen L. Craig, Tomás Martín, Julius Rebek, Jr. Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2130::AID-ANIE2130>3.0.CO;2-K |
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A Supramolecular Solution to a Long-Standing Problem: The 1,6-Polymerization of a Triacetylene Jun Xiao, Meng Yang, Joseph W. Lauher, Frank W. Fowler Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2132::AID-ANIE2132>3.0.CO;2-8 |
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Mixed Ferrocene-Cobaltocenium Dendrimers: The Most Stable Organometallic Redox Systems Combined in a Dendritic Molecule
Carmen M. Casado, Blanca González, Isabel Cuadrado, Beatriz Alonso, Moisés Morán, Jos?Losada Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2135::AID-ANIE2135>3.0.CO;2-R |
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Structure of Homoleptic CuI(CO)3 Cations in CuI-Exchanged ZSM-5 Zeolite: An X-ray Absorption Study Carlo Lamberti, Gemma Turnes Palomino, Silvia Bordiga, Gloria Berlier, Francesco D'Acapito, Adriano Zecchina Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2138::AID-ANIE2138>3.0.CO;2-9 |
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Nickel-Catalyzed Generation of Schiff Base Aluminum Enolate Initiators for Controlled Methacrylate Polymerization Paul A. Cameron, Vernon C. Gibson, Derek J. Irvine Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2141::AID-ANIE2141>3.0.CO;2-C |
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Reactive Intermediates on Metal Surfaces: A Ketene Monolayer on Single Crystal Platinum Generated by Photolysis of Pyridyl -Diazoketones Jason L. Pitters, Keith Griffiths, Milan Kovar, Peter R. Norton, Mark S. Workentin Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2144::AID-ANIE2144>3.0.CO;2-V |
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Expanding the Scope of Protein Biosynthesis by Altering the Methionyl-tRNA Synthetase Activity of a Bacterial Expression Host Kristi L. Kiick, Jan C. M. van Hest, David A. Tirrell Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2148::AID-ANIE2148>3.0.CO;2-7 |
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A Highly Efficient Triplet Analogue of a Thermal Biradical Cyclization - The Photochemical C2-C6 Cyclization of Enyne-Heteroallenes
Michael Schmittel, David Rodríguez, Jens-Peter Steffen Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2152::AID-ANIE2152>3.0.CO;2-4 |
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A Chiral Nonracemic Enolate with Dynamic Axial Chirality: Direct Asymmetric -Methylation of -Amino Acid Derivatives Takeo Kawabata, Hideo Suzuki, Yosikazu Nagae, Kaoru Fuji Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2155::AID-ANIE2155>3.0.CO;2-N |
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Generation of Heteroatom-Substituted Carbene Complexes of Iridium by Double C-H Activation of Ether and Amine Substrates Christian Slugovc, Kurt Mereiter, Swiatoslaw Trofimenko, Ernesto Carmona Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2158::AID-ANIE2158>3.0.CO;2-5 |
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DesVI: A New Member of the Sugar N,N-Dimethyltransferase Family Involved in the Biosynthesis of Desosamine Cheng-wei Chang, Lishan Zhao, Hiroshi Yamase, Hung-wen Liu Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2160::AID-ANIE2160>3.0.CO;2-E |
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Surface-Confined Light Harvesting, Energy Transfer, and Amplification of Fluorescence Emission in Chromophore-Labeled Self-Assembled Monolayers
Lysander A. J. Chrisstoffels, Alex Adronov, Jean M. J. Fréchet Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2163::AID-ANIE2163>3.0.CO;2-X |
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An Anthracene-Based Photochromic System That Responds to Two Chemical Inputs Gordon McSkimming, James H. R. Tucker, Henri Bouas-Laurent, Jean-Pierre Desvergne Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2167::AID-ANIE2167>3.0.CO;2-9 |
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Evidence for Cooperativity in the Disproportionation of H2O2 Efficiently Catalyzed by a Tetranuclear Manganese Complex Christopher E. Dub? David W. Wright, William H. Armstrong Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2169::AID-ANIE2169>3.0.CO;2-Y |
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A Practical Asymmetric Synthesis of Enantiomerically Pure 3-Substituted Pyroglutamic Acids and Related Compounds Vadim A. Soloshonok, Chaozhong Cai, Victor J. Hruby Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2172::AID-ANIE2172>3.0.CO;2-0 |
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A Rapid Total Synthesis of Spirotryprostatin B: Proof of Its Relative and Absolute Stereochemistry Franz von Nussbaum, Samuel J. Danishefsky Published Online: 14 Jun 2000 DOI10.1002/1521-3773(20000616)39:12<2175::AID-ANIE2175>3.0.CO;2-J |